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Deep-sea hydrothermal vents inject dissolved and particulate metals, dissolved gasses, and biological matter into the water column, creating plumes several hundred meters above the seafloor that can be traced thousands of kilometers. To understand the impact of these plumes, rosettes equipped with sample bottles and in situ instruments, e.g., for turbidity, oxidation-reduction potential, and temperature, have been key tools for collecting water column fluid for informative ex situ analysis. However, deploying rosettes strategically in distal (>1km) plume-derived fluids is difficult when plume material is entrained rapidly with background water and transported by complicated bathymetric, internal, and/or tidal currents. This problem is exacerbated when the controlling dynamics are also poorly constrained (e.g., no persistent monitoring, few historical data) and data collected while in the field to estimate or compensate for these dynamics are only available to be analyzed hours or days following an asset deployment. Autonomous underwater vehicles (AUVs) equipped with equivalent in situ instruments to rosettes excel at exploration missions and creating highly-resolved maps at different spatial scales. Utilization of AUVs for hydrothermal plume charting and strategic sampling with rosettes is at a techno-scientific frontier that requires new data transmission and visualization interfaces for supporting real-time evidence-based operational decisions made at sea. We formulated a method for monitoring in situ water properties while an AUV is underway that (1) builds situational awareness of deep fluid mass distributions, (2) allows scientists-in-the-loop to rapidly identify fluid distribution patterns that inform adaptations to AUV missions or deployments of other assets, like rosettes, for targeted sample collection, and (3) supports robust formulation of working hypotheses of plume dynamics for in-field investigation. We will present a description of the method with preliminary results from cruise AT50-15 (Juan de Fuca Ridge, 2023) using AUV Sentry and discuss how supervised autonomy will improve ocean robotics for future science missions.